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Mechanical compatibility of sol–gel annealing with titanium for orthopaedic prostheses

机译:用于矫形假体的溶胶 - 凝胶退火与钛的机械相容性

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摘要

Sol–gel processing is an attractive method for large-scale surface coating due to its facile and inexpensive preparation, even with the inclusion of precision nanotopographies. These are desirable traits for metal orthopaedic prostheses where ceramic coatings are known to be osteoinductive and the effects may be amplified through nanotexturing. However there are a few concerns associated with the application of sol–gel technology to orthopaedics. Primarily, the annealing stage required to transform the sol–gel into a ceramic may compromise the physical integrity of the underlying metal. Secondly, loose particles on medical implants can be carcinogenic and cause inflammation so the coating needs to be strongly bonded to the implant. These concerns are addressed in this paper. Titanium, the dominant material for orthopaedics at present, is examined before and after sol–gel processing for changes in hardness and flexural modulus. Wear resistance, bending and pull tests are also performed to evaluate the ceramic coating. The findings suggest that sol–gel coatings will be compatible with titanium implants for an optimum temperature of 500 °C.
机译:溶胶-凝胶法加工简便,价格低廉,即使包括精密的纳米形貌图,对于大规模表面涂覆也是一种有吸引力的方法。这些是金属矫形假体的理想特性,其中陶瓷涂层已知具有骨诱导作用,并且可以通过纳米纹理放大效果。但是,溶胶凝胶技术在骨科中的应用存在一些问题。首先,将溶胶-凝胶转变成陶瓷所需的退火阶段可能会损害底层金属的物理完整性。其次,医用植入物上的松散颗粒可能致癌并引起炎症,因此涂层需要牢固地粘结到植入物上。这些关注点在本文中得到解决。钛是目前骨科的主要材料,在溶胶-凝胶加工之前和之后都要检查其硬度和弯曲模量的变化。还进行了耐磨性,弯曲和拉力测试,以评估陶瓷涂层。研究结果表明,溶胶-凝胶涂层在500°C的最佳温度下将与钛植入物兼容。

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